This dataset provides modelled annual average near-ground atmospheric composition for Scotland for the key air pollutants nitrogen dioxide, total nitrogen oxides, sulphur dioxide, and fine particulate matter for the year 2023. As well as total concentrations, the dataset includes concentration contributions from domestic solid fuel burning. The dataset was created with the European Monitoring and Evaluation Programme (EMEP) model version 5.5 and the Weather Research and Forecasting (WRF) model version 4.4.2. It was generated under a Scottish Government project which also calculated emissions from domestic solid fuel burning in Scotland and carried out measurements targeting the air pollution impacts of solid fuel burning in Scotland. Full details about this dataset can be found at https://doi.org/10.5285/9123cb2b-739d-43cb-b00a-9678a41fc24a